Articulo de referencia

Tabla de armónicos esféricos

Esta es una tabla de armónicos esféricos ortonormalizados que emplean la fase de Condon-Shortley hasta el grado ℓ = 10 {\displaystyle \ell =10} Algunas de estas fórmulas se expr...

Esta es una tabla de armónicos esféricos ortonormalizados que emplean la fase de Condon-Shortley hasta el grado=10{\displaystyle \ell =10}Algunas de estas fórmulas se expresan en términos de la expansión cartesiana de los armónicos esféricos en polinomios en x , y , z y r . Para los fines de esta tabla, es útil expresar las transformaciones habituales de esféricas a cartesianas que relacionan estos componentes cartesianos conθ{\displaystyle \theta }yφ{\displaystyle \varphi }como

{porque(θ)=z/rmi±iφpecado(θ)=(incógnita±iy)/r{\displaystyle {\begin{cases}\cos(\theta )&=z/r\\e^{\pm i\varphi }\cdot \sin(\theta )&=(x\pm iy)/r\end{cases}}}

Armónicos esféricos complejos

Para = 0, …, 5, véase. [ 1 ]

= 0

Y00(θ,φ)=121π{\displaystyle Y_{0}^{0}(\theta,\varphi)={1 \over 2}{\sqrt {1 \over \pi }}}

= 1

Y11(θ,φ)=1232πmiiφpecadoθ=1232π(incógnitaiy)rY10(θ,φ)=123πporqueθ=123πzrY11(θ,φ)=1232πmiiφpecadoθ=1232π(incógnita+iy)r{\displaystyle {\begin{aligned}Y_{1}^{-1}(\theta ,\varphi )&=&&{1 \over 2}{\sqrt {3 \over 2\pi }}\cdot \mathrm {e} ^{-i\varphi }\cdot \sin \theta &&=&&{1 \over 2}{\sqrt {3 \over 2\pi }}\cdot {(x-iy) \over r}\\Y_{1}^{0}(\theta ,\varphi )&=&&{1 \over 2}{\sqrt {3 \over \pi }}\cdot \cos \theta &&=&&{1 \over 2}{\sqrt {3 \over \pi }}\cdot {z \over r}\\Y_{1}^{1}(\theta ,\varphi )&=&-&{1 \over 2}{\sqrt {3 \over 2\pi }}\cdot \mathrm {e} ^{i\varphi }\cdot \sin \theta &&=&-&{1 \over 2}{\sqrt {3 \over 2\pi }}\cdot {(x+iy) \over r}\end{aligned}}}

= 2

Y22(θ,φ)=14152πmi2iφpecado2θ=14152π(incógnitaiy)2r2Y21(θ,φ)=12152πmiiφpecadoθporqueθ=12152π(incógnitaiy)zr2Y20(θ,φ)=145π(3porque2θ1)=145π(3z2r2)r2Y21(θ,φ)=12152πmiiφpecadoθporqueθ=12152π(incógnita+iy)zr2Y22(θ,φ)=14152πmi2iφpecado2θ=14152π(incógnita+iy)2r2{\displaystyle {\begin{aligned}Y_{2}^{-2}(\theta ,\varphi )&=&&{1 \over 4}{\sqrt {15 \over 2\pi }}\cdot \mathrm {e} ^{-2i\varphi }\cdot \sin ^{2}\theta \quad &&=&&{1 \over 4}{\sqrt {15 \over 2\pi }}\cdot {(x-iy)^{2} \over r^{2}}&\\Y_{2}^{-1}(\theta ,\varphi )&=&&{1 \over 2}{\sqrt {15 \over 2\pi }}\cdot \mathrm {e} ^{-i\varphi }\cdot \sin \theta \cdot \cos \theta \quad &&=&&{1 \over 2}{\sqrt {15 \over 2\pi }}\cdot {(x-iy)\cdot z \over r^{2}}&\\Y_{2}^{0}(\theta ,\varphi )&=&&{1 \over 4}{\sqrt {5 \over \pi }}\cdot (3\cos ^{2}\theta -1)\quad &&=&&{1 \over 4}{\sqrt {5 \over \pi }}\cdot {(3z^{2}-r^{2}) \over r^{2}}&\\Y_{2}^{1}(\theta ,\varphi )&=&-&{1 \over 2}{\sqrt {15 \over 2\pi }}\cdot \mathrm {e} ^{i\varphi }\cdot \sin \theta \cdot \cos \theta \quad &&=&-&{1 \over 2}{\sqrt {15 \over 2\pi }}\cdot {(x+iy)\cdot z \over r^{2}}&\\Y_{2}^{2}(\theta ,\varphi )&=&&{1 \over 4}{\sqrt {15 \over 2\pi }}\cdot \mathrm {e} ^{2i\varphi }\cdot \sin ^{2}\theta \quad &&=&&{1 \over 4}{\sqrt {15 \over 2\pi }}\cdot {(x+iy)^{2} \over r^{2}}&\end{aligned}}}

= 3

Y33(θ,φ)=1835πmi3iφpecado3θ=1835π(incógnitaiy)3r3Y32(θ,φ)=141052πmi2iφpecado2θporqueθ=141052π(incógnitaiy)2zr3Y31(θ,φ)=1821πmiiφpecadoθ(5porque2θ1)=1821π(incógnitaiy)(5z2r2)r3Y30(θ,φ)=147π(5porque3θ3porqueθ)=147π(5z33zr2)r3Y31(θ,φ)=1821πmiiφpecadoθ(5porque2θ1)=1821π(incógnita+iy)(5z2r2)r3Y32(θ,φ)=141052πmi2iφpecado2θporqueθ=141052π(incógnita+iy)2zr3Y33(θ,φ)=1835πmi3iφpecado3θ=1835π(incógnita+iy)3r3{\displaystyle {\begin{aligned}Y_{3}^{-3}(\theta ,\varphi )&=&&{1 \over 8}{\sqrt {35 \over \pi }}\cdot \mathrm {e} ^{-3i\varphi }\cdot \sin ^{3}\theta \quad &&=&&{1 \over 8}{\sqrt {35 \over \pi }}\cdot {(x-iy)^{3} \over r^{3}}&\\Y_{3}^{-2}(\theta ,\varphi )&=&&{1 \over 4}{\sqrt {105 \over 2\pi }}\cdot \mathrm {e} ^{-2i\varphi }\cdot \sin ^{2}\theta \cdot \cos \theta \quad &&=&&{1 \over 4}{\sqrt {105 \over 2\pi }}\cdot {(x-iy)^{2}\cdot z \over r^{3}}&\\Y_{3}^{-1}(\theta ,\varphi )&=&&{1 \over 8}{\sqrt {21 \over \pi }}\cdot \mathrm {e} ^{-i\varphi }\cdot \sin \theta \cdot (5\cos ^{2}\theta -1)\quad &&=&&{1 \over 8}{\sqrt {21 \over \pi }}\cdot {(x-iy)\cdot (5z^{2}-r^{2}) \over r^{3}}&\\Y_{3}^{0}(\theta ,\varphi )&=&&{1 \over 4}{\sqrt {7 \over \pi }}\cdot (5\cos ^{3}\theta -3\cos \theta )\quad &&=&&{1 \over 4}{\sqrt {7 \over \pi }}\cdot {(5z^{3}-3zr^{2}) \over r^{3}}&\\Y_{3}^{1}(\theta ,\varphi )&=&-&{1 \over 8}{\sqrt {21 \over \pi }}\cdot \mathrm {e} ^{i\varphi }\cdot \sin \theta \cdot (5\cos ^{2}\theta -1)\quad &&=&&{-1 \over 8}{\sqrt {21 \over \pi }}\cdot {(x+iy)\cdot (5z^{2}-r^{2}) \over r^{3}}&\\Y_{3}^{2}(\theta ,\varphi )&=&&{1 \over 4}{\sqrt {105 \over 2\pi }}\cdot \mathrm {e} ^{2i\varphi }\cdot \sin ^{2}\theta \cdot \cos \theta \quad &&=&&{1 \over 4}{\sqrt {105 \over 2\pi }}\cdot {(x+iy)^{2}\cdot z \over r^{3}}&\\Y_{3}^{3}(\theta ,\varphi )&=&-&{1 \over 8}{\sqrt {35 \over \pi }}\cdot \mathrm {e} ^{3i\varphi }\cdot \sin ^{3}\theta \quad &&=&&{-1 \over 8}{\sqrt {35 \over \pi }}\cdot {(x+iy)^{3} \over r^{3}}&\end{aligned}}}

= 4

Y44(θ,φ)=316352πmi4iφpecado4θ=316352π(incógnitaiy)4r4Y43(θ,φ)=3835πmi3iφpecado3θporqueθ=3835π(incógnitaiy)3zr4Y42(θ,φ)=3852πmi2iφpecado2θ(7porque2θ1)=3852π(incógnitaiy)2(7z2r2)r4Y41(θ,φ)=385πmiiφpecadoθ(7porque3θ3porqueθ)=385π(incógnitaiy)(7z33zr2)r4Y40(θ,φ)=3161π(35porque4θ30porque2θ+3)=3161π(35z430z2r2+3r4)r4Y41(θ,φ)=385πmiiφpecadoθ(7porque3θ3porqueθ)=385π(incógnita+iy)(7z33zr2)r4Y42(θ,φ)=3852πmi2iφpecado2θ(7porque2θ1)=3852π(incógnita+iy)2(7z2r2)r4Y43(θ,φ)=3835πmi3iφpecado3θporqueθ=3835π(incógnita+iy)3zr4Y44(θ,φ)=316352πmi4iφpecado4θ=316352π(incógnita+iy)4r4{\displaystyle {\begin{aligned}Y_{4}^{-4}(\theta ,\varphi )&=&&{3 \over 16}{\sqrt {35 \over 2\pi }}\cdot \mathrm {e} ^{-4i\varphi }\cdot \sin ^{4}\theta &&=&&{\frac {3}{16}}{\sqrt {\frac {35}{2\pi }}}\cdot {\frac {(x-iy)^{4}}{r^{4}}}\\Y_{4}^{-3}(\theta ,\varphi )&=&&{3 \over 8}{\sqrt {35 \over \pi }}\cdot \mathrm {e} ^{-3i\varphi }\cdot \sin ^{3}\theta \cdot \cos \theta &&=&&{\frac {3}{8}}{\sqrt {\frac {35}{\pi }}}\cdot {\frac {(x-iy)^{3}z}{r^{4}}}\\Y_{4}^{-2}(\theta ,\varphi )&=&&{3 \over 8}{\sqrt {5 \over 2\pi }}\cdot \mathrm {e} ^{-2i\varphi }\cdot \sin ^{2}\theta \cdot (7\cos ^{2}\theta -1)&&=&&{\frac {3}{8}}{\sqrt {\frac {5}{2\pi }}}\cdot {\frac {(x-iy)^{2}\cdot (7z^{2}-r^{2})}{r^{4}}}\\Y_{4}^{-1}(\theta ,\varphi )&=&&{3 \over 8}{\sqrt {5 \over \pi }}\cdot \mathrm {e} ^{-i\varphi }\cdot \sin \theta \cdot (7\cos ^{3}\theta -3\cos \theta )&&=&&{\frac {3}{8}}{\sqrt {\frac {5}{\pi }}}\cdot {\frac {(x-iy)\cdot (7z^{3}-3zr^{2})}{r^{4}}}\\Y_{4}^{0}(\theta ,\varphi )&=&&{3 \over 16}{\sqrt {1 \over \pi }}\cdot (35\cos ^{4}\theta -30\cos ^{2}\theta +3)&&=&&{\frac {3}{16}}{\sqrt {\frac {1}{\pi }}}\cdot {\frac {(35z^{4}-30z^{2}r^{2}+3r^{4})}{r^{4}}}\\Y_{4}^{1}(\theta ,\varphi )&=&&{-3 \over 8}{\sqrt {5 \over \pi }}\cdot \mathrm {e} ^{i\varphi }\cdot \sin \theta \cdot (7\cos ^{3}\theta -3\cos \theta )&&=&&{\frac {-3}{8}}{\sqrt {\frac {5}{\pi }}}\cdot {\frac {(x+iy)\cdot (7z^{3}-3zr^{2})}{r^{4}}}\\Y_{4}^{2}(\theta ,\varphi )&=&&{3 \over 8}{\sqrt {5 \over 2\pi }}\cdot \mathrm {e} ^{2i\varphi }\cdot \sin ^{2}\theta \cdot (7\cos ^{2}\theta -1)&&=&&{\frac {3}{8}}{\sqrt {\frac {5}{2\pi }}}\cdot {\frac {(x+iy)^{2}\cdot (7z^{2}-r^{2})}{r^{4}}}\\Y_{4}^{3}(\theta ,\varphi )&=&&{-3 \over 8}{\sqrt {35 \over \pi }}\cdot \mathrm {e} ^{3i\varphi }\cdot \sin ^{3}\theta \cdot \cos \theta &&=&&{\frac {-3}{8}}{\sqrt {\frac {35}{\pi }}}\cdot {\frac {(x+iy)^{3}z}{r^{4}}}\\Y_{4}^{4}(\theta ,\varphi )&=&&{3 \over 16}{\sqrt {35 \over 2\pi }}\cdot \mathrm {e} ^{4i\varphi }\cdot \sin ^{4}\theta &&=&&{\frac {3}{16}}{\sqrt {\frac {35}{2\pi }}}\cdot {\frac {(x+iy)^{4}}{r^{4}}}\end{aligned}}}

= 5

Y55(θ,φ)=33277πmi5iφpecado5θY54(θ,φ)=3163852πmi4iφpecado4θporqueθY53(θ,φ)=132385πmi3iφpecado3θ(9porque2θ1)Y52(θ,φ)=1811552πmi2iφpecado2θ(3porque3θporqueθ)Y51(θ,φ)=1161652πmiiφpecadoθ(21porque4θ14porque2θ+1)Y50(θ,φ)=11611π(63porque5θ70porque3θ+15porqueθ)Y51(θ,φ)=1161652πmiiφpecadoθ(21porque4θ14porque2θ+1)Y52(θ,φ)=1811552πmi2iφpecado2θ(3porque3θporqueθ)Y53(θ,φ)=132385πmi3iφpecado3θ(9porque2θ1)Y54(θ,φ)=3163852πmi4iφpecado4θporqueθY55(θ,φ)=33277πmi5iφpecado5θ{\displaystyle {\begin{aligned}Y_{5}^{-5}(\theta ,\varphi )&={3 \over 32}{\sqrt {77 \over \pi }}\cdot \mathrm {e} ^{-5i\varphi }\cdot \sin ^{5}\theta \\Y_{5}^{-4}(\theta ,\varphi )&={3 \over 16}{\sqrt {385 \over 2\pi }}\cdot \mathrm {e} ^{-4i\varphi }\cdot \sin ^{4}\theta \cdot \cos \theta \\Y_{5}^{-3}(\theta ,\varphi )&={1 \over 32}{\sqrt {385 \over \pi }}\cdot \mathrm {e} ^{-3i\varphi }\cdot \sin ^{3}\theta \cdot (9\cos ^{2}\theta -1)\\Y_{5}^{-2}(\theta ,\varphi )&={1 \over 8}{\sqrt {1155 \over 2\pi }}\cdot \mathrm {e} ^{-2i\varphi }\cdot \sin ^{2}\theta \cdot (3\cos ^{3}\theta -\cos \theta )\\Y_{5}^{-1}(\theta ,\varphi )&={1 \over 16}{\sqrt {165 \over 2\pi }}\cdot \mathrm {e} ^{-i\varphi }\cdot \sin \theta \cdot (21\cos ^{4}\theta -14\cos ^{2}\theta +1)\\Y_{5}^{0}(\theta ,\varphi )&={1 \over 16}{\sqrt {11 \over \pi }}\cdot (63\cos ^{5}\theta -70\cos ^{3}\theta +15\cos \theta )\\Y_{5}^{1}(\theta ,\varphi )&={-1 \over 16}{\sqrt {165 \over 2\pi }}\cdot \mathrm {e} ^{i\varphi }\cdot \sin \theta \cdot (21\cos ^{4}\theta -14\cos ^{2}\theta +1)\\Y_{5}^{2}(\theta ,\varphi )&={1 \over 8}{\sqrt {1155 \over 2\pi }}\cdot \mathrm {e} ^{2i\varphi }\cdot \sin ^{2}\theta \cdot (3\cos ^{3}\theta -\cos \theta )\\Y_{5}^{3}(\theta ,\varphi )&={-1 \over 32}{\sqrt {385 \over \pi }}\cdot \mathrm {e} ^{3i\varphi }\cdot \sin ^{3}\theta \cdot (9\cos ^{2}\theta -1)\\Y_{5}^{4}(\theta ,\varphi )&={3 \over 16}{\sqrt {385 \over 2\pi }}\cdot \mathrm {e} ^{4i\varphi }\cdot \sin ^{4}\theta \cdot \cos \theta \\Y_{5}^{5}(\theta ,\varphi )&={-3 \over 32}{\sqrt {77 \over \pi }}\cdot \mathrm {e} ^{5i\varphi }\cdot \sin ^{5}\theta \end{aligned}}}

= 6

Y66(θ,φ)=1643003πmi6iφpecado6θY65(θ,φ)=3321001πmi5iφpecado5θporqueθY64(θ,φ)=332912πmi4iφpecado4θ(11porque2θ1)Y63(θ,φ)=1321365πmi3iφpecado3θ(11porque3θ3porqueθ)Y62(θ,φ)=1641365πmi2iφpecado2θ(33porque4θ18porque2θ+1)Y61(θ,φ)=1162732πmiiφpecadoθ(33porque5θ30porque3θ+5porqueθ)Y60(θ,φ)=13213π(231porque6θ315porque4θ+105porque2θ5)Y61(θ,φ)=1162732πmiiφpecadoθ(33porque5θ30porque3θ+5porqueθ)Y62(θ,φ)=1641365πmi2iφpecado2θ(33porque4θ18porque2θ+1)Y63(θ,φ)=1321365πmi3iφpecado3θ(11porque3θ3porqueθ)Y64(θ,φ)=332912πmi4iφpecado4θ(11porque2θ1)Y65(θ,φ)=3321001πmi5iφpecado5θporqueθY66(θ,φ)=1643003πmi6iφpecado6θ{\displaystyle {\begin{aligned}Y_{6}^{-6}(\theta ,\varphi )&={1 \over 64}{\sqrt {3003 \over \pi }}\cdot \mathrm {e} ^{-6i\varphi }\cdot \sin ^{6}\theta \\Y_{6}^{-5}(\theta ,\varphi )&={3 \over 32}{\sqrt {1001 \over \pi }}\cdot \mathrm {e} ^{-5i\varphi }\cdot \sin ^{5}\theta \cdot \cos \theta \\Y_{6}^{-4}(\theta ,\varphi )&={3 \over 32}{\sqrt {91 \over 2\pi }}\cdot \mathrm {e} ^{-4i\varphi }\cdot \sin ^{4}\theta \cdot (11\cos ^{2}\theta -1)\\Y_{6}^{-3}(\theta ,\varphi )&={1 \over 32}{\sqrt {1365 \over \pi }}\cdot \mathrm {e} ^{-3i\varphi }\cdot \sin ^{3}\theta \cdot (11\cos ^{3}\theta -3\cos \theta )\\Y_{6}^{-2}(\theta ,\varphi )&={1 \over 64}{\sqrt {1365 \over \pi }}\cdot \mathrm {e} ^{-2i\varphi }\cdot \sin ^{2}\theta \cdot (33\cos ^{4}\theta -18\cos ^{2}\theta +1)\\Y_{6}^{-1}(\theta ,\varphi )&={1 \over 16}{\sqrt {273 \over 2\pi }}\cdot \mathrm {e} ^{-i\varphi }\cdot \sin \theta \cdot (33\cos ^{5}\theta -30\cos ^{3}\theta +5\cos \theta )\\Y_{6}^{0}(\theta ,\varphi )&={1 \over 32}{\sqrt {13 \over \pi }}\cdot (231\cos ^{6}\theta -315\cos ^{4}\theta +105\cos ^{2}\theta -5)\\Y_{6}^{1}(\theta ,\varphi )&=-{1 \over 16}{\sqrt {273 \over 2\pi }}\cdot \mathrm {e} ^{i\varphi }\cdot \sin \theta \cdot (33\cos ^{5}\theta -30\cos ^{3}\theta +5\cos \theta )\\Y_{6}^{2}(\theta ,\varphi )&={1 \over 64}{\sqrt {1365 \over \pi }}\cdot \mathrm {e} ^{2i\varphi }\cdot \sin ^{2}\theta \cdot (33\cos ^{4}\theta -18\cos ^{2}\theta +1)\\Y_{6}^{3}(\theta ,\varphi )&=-{1 \over 32}{\sqrt {1365 \over \pi }}\cdot \mathrm {e} ^{3i\varphi }\cdot \sin ^{3}\theta \cdot (11\cos ^{3}\theta -3\cos \theta )\\Y_{6}^{4}(\theta ,\varphi )&={3 \over 32}{\sqrt {91 \over 2\pi }}\cdot \mathrm {e} ^{4i\varphi }\cdot \sin ^{4}\theta \cdot (11\cos ^{2}\theta -1)\\Y_{6}^{5}(\theta ,\varphi )&=-{3 \over 32}{\sqrt {1001 \over \pi }}\cdot \mathrm {e} ^{5i\varphi }\cdot \sin ^{5}\theta \cdot \cos \theta \\Y_{6}^{6}(\theta ,\varphi )&={1 \over 64}{\sqrt {3003 \over \pi }}\cdot \mathrm {e} ^{6i\varphi }\cdot \sin ^{6}\theta \end{aligned}}}

= 7

Y77(θ,φ)=3647152πmi7iφpecado7θY76(θ,φ)=3645005πmi6iφpecado6θporqueθY75(θ,φ)=3643852πmi5iφpecado5θ(13porque2θ1)Y74(θ,φ)=3323852πmi4iφpecado4θ(13porque3θ3porqueθ)Y73(θ,φ)=364352πmi3iφpecado3θ(143porque4θ66porque2θ+3)Y72(θ,φ)=36435πmi2iφpecado2θ(143porque5θ110porque3θ+15porqueθ)Y71(θ,φ)=1641052πmiiφpecadoθ(429porque6θ495porque4θ+135porque2θ5)Y70(θ,φ)=13215π(429porque7θ693porque5θ+315porque3θ35porqueθ)Y71(θ,φ)=1641052πmiiφpecadoθ(429porque6θ495porque4θ+135porque2θ5)Y72(θ,φ)=36435πmi2iφpecado2θ(143porque5θ110porque3θ+15porqueθ)Y73(θ,φ)=364352πmi3iφpecado3θ(143porque4θ66porque2θ+3)Y74(θ,φ)=3323852πmi4iφpecado4θ(13porque3θ3porqueθ)Y75(θ,φ)=3643852πmi5iφpecado5θ(13porque2θ1)Y76(θ,φ)=3645005πmi6iφpecado6θporqueθY77(θ,φ)=3647152πmi7iφpecado7θ{\displaystyle {\begin{aligned}Y_{7}^{-7}(\theta ,\varphi )&={3 \over 64}{\sqrt {715 \over 2\pi }}\cdot \mathrm {e} ^{-7i\varphi }\cdot \sin ^{7}\theta \\Y_{7}^{-6}(\theta ,\varphi )&={3 \over 64}{\sqrt {5005 \over \pi }}\cdot \mathrm {e} ^{-6i\varphi }\cdot \sin ^{6}\theta \cdot \cos \theta \\Y_{7}^{-5}(\theta ,\varphi )&={3 \over 64}{\sqrt {385 \over 2\pi }}\cdot \mathrm {e} ^{-5i\varphi }\cdot \sin ^{5}\theta \cdot (13\cos ^{2}\theta -1)\\Y_{7}^{-4}(\theta ,\varphi )&={3 \over 32}{\sqrt {385 \over 2\pi }}\cdot \mathrm {e} ^{-4i\varphi }\cdot \sin ^{4}\theta \cdot (13\cos ^{3}\theta -3\cos \theta )\\Y_{7}^{-3}(\theta ,\varphi )&={3 \over 64}{\sqrt {35 \over 2\pi }}\cdot \mathrm {e} ^{-3i\varphi }\cdot \sin ^{3}\theta \cdot (143\cos ^{4}\theta -66\cos ^{2}\theta +3)\\Y_{7}^{-2}(\theta ,\varphi )&={3 \over 64}{\sqrt {35 \over \pi }}\cdot \mathrm {e} ^{-2i\varphi }\cdot \sin ^{2}\theta \cdot (143\cos ^{5}\theta -110\cos ^{3}\theta +15\cos \theta )\\Y_{7}^{-1}(\theta ,\varphi )&={1 \over 64}{\sqrt {105 \over 2\pi }}\cdot \mathrm {e} ^{-i\varphi }\cdot \sin \theta \cdot (429\cos ^{6}\theta -495\cos ^{4}\theta +135\cos ^{2}\theta -5)\\Y_{7}^{0}(\theta ,\varphi )&={1 \over 32}{\sqrt {15 \over \pi }}\cdot (429\cos ^{7}\theta -693\cos ^{5}\theta +315\cos ^{3}\theta -35\cos \theta )\\Y_{7}^{1}(\theta ,\varphi )&=-{1 \over 64}{\sqrt {105 \over 2\pi }}\cdot \mathrm {e} ^{i\varphi }\cdot \sin \theta \cdot (429\cos ^{6}\theta -495\cos ^{4}\theta +135\cos ^{2}\theta -5)\\Y_{7}^{2}(\theta ,\varphi )&={3 \over 64}{\sqrt {35 \over \pi }}\cdot \mathrm {e} ^{2i\varphi }\cdot \sin ^{2}\theta \cdot (143\cos ^{5}\theta -110\cos ^{3}\theta +15\cos \theta )\\Y_{7}^{3}(\theta ,\varphi )&=-{3 \over 64}{\sqrt {35 \over 2\pi }}\cdot \mathrm {e} ^{3i\varphi }\cdot \sin ^{3}\theta \cdot (143\cos ^{4}\theta -66\cos ^{2}\theta +3)\\Y_{7}^{4}(\theta ,\varphi )&={3 \over 32}{\sqrt {385 \over 2\pi }}\cdot \mathrm {e} ^{4i\varphi }\cdot \sin ^{4}\theta \cdot (13\cos ^{3}\theta -3\cos \theta )\\Y_{7}^{5}(\theta ,\varphi )&=-{3 \over 64}{\sqrt {385 \over 2\pi }}\cdot \mathrm {e} ^{5i\varphi }\cdot \sin ^{5}\theta \cdot (13\cos ^{2}\theta -1)\\Y_{7}^{6}(\theta ,\varphi )&={3 \over 64}{\sqrt {5005 \over \pi }}\cdot \mathrm {e} ^{6i\varphi }\cdot \sin ^{6}\theta \cdot \cos \theta \\Y_{7}^{7}(\theta ,\varphi )&=-{3 \over 64}{\sqrt {715 \over 2\pi }}\cdot \mathrm {e} ^{7i\varphi }\cdot \sin ^{7}\theta \end{aligned}}}

= 8

Y88(θ,φ)=3256121552πmi8iφpecado8θY87(θ,φ)=364121552πmi7iφpecado7θporqueθY86(θ,φ)=11287293πmi6iφpecado6θ(15porque2θ1)Y85(θ,φ)=364170172πmi5iφpecado5θ(5porque3θporqueθ)Y84(θ,φ)=312813092πmi4iφpecado4θ(65porque4θ26porque2θ+1)Y83(θ,φ)=164196352πmi3iφpecado3θ(39porque5θ26porque3θ+3porqueθ)Y82(θ,φ)=3128595πmi2iφpecado2θ(143porque6θ143porque4θ+33porque2θ1)Y81(θ,φ)=364172πmiiφpecadoθ(715porque7θ1001porque5θ+385porque3θ35porqueθ)Y80(θ,φ)=125617π(6435porque8θ12012porque6θ+6930porque4θ1260porque2θ+35)Y81(θ,φ)=364172πmiiφpecadoθ(715porque7θ1001porque5θ+385porque3θ35porqueθ)Y82(θ,φ)=3128595πmi2iφpecado2θ(143porque6θ143porque4θ+33porque2θ1)Y83(θ,φ)=164196352πmi3iφpecado3θ(39porque5θ26porque3θ+3porqueθ)Y84(θ,φ)=312813092πmi4iφpecado4θ(65porque4θ26porque2θ+1)Y85(θ,φ)=364170172πmi5iφpecado5θ(5porque3θporqueθ)Y86(θ,φ)=11287293πmi6iφpecado6θ(15porque2θ1)Y87(θ,φ)=364121552πmi7iφpecado7θporqueθY88(θ,φ)=3256121552πmi8iφpecado8θ{\displaystyle {\begin{aligned}Y_{8}^{-8}(\theta ,\varphi )&={3 \over 256}{\sqrt {12155 \over 2\pi }}\cdot \mathrm {e} ^{-8i\varphi }\cdot \sin ^{8}\theta \\Y_{8}^{-7}(\theta ,\varphi )&={3 \over 64}{\sqrt {12155 \over 2\pi }}\cdot \mathrm {e} ^{-7i\varphi }\cdot \sin ^{7}\theta \cdot \cos \theta \\Y_{8}^{-6}(\theta ,\varphi )&={1 \over 128}{\sqrt {7293 \over \pi }}\cdot \mathrm {e} ^{-6i\varphi }\cdot \sin ^{6}\theta \cdot (15\cos ^{2}\theta -1)\\Y_{8}^{-5}(\theta ,\varphi )&={3 \over 64}{\sqrt {17017 \over 2\pi }}\cdot \mathrm {e} ^{-5i\varphi }\cdot \sin ^{5}\theta \cdot (5\cos ^{3}\theta -\cos \theta )\\Y_{8}^{-4}(\theta ,\varphi )&={3 \over 128}{\sqrt {1309 \over 2\pi }}\cdot \mathrm {e} ^{-4i\varphi }\cdot \sin ^{4}\theta \cdot (65\cos ^{4}\theta -26\cos ^{2}\theta +1)\\Y_{8}^{-3}(\theta ,\varphi )&={1 \over 64}{\sqrt {19635 \over 2\pi }}\cdot \mathrm {e} ^{-3i\varphi }\cdot \sin ^{3}\theta \cdot (39\cos ^{5}\theta -26\cos ^{3}\theta +3\cos \theta )\\Y_{8}^{-2}(\theta ,\varphi )&={3 \over 128}{\sqrt {595 \over \pi }}\cdot \mathrm {e} ^{-2i\varphi }\cdot \sin ^{2}\theta \cdot (143\cos ^{6}\theta -143\cos ^{4}\theta +33\cos ^{2}\theta -1)\\Y_{8}^{-1}(\theta ,\varphi )&={3 \over 64}{\sqrt {17 \over 2\pi }}\cdot \mathrm {e} ^{-i\varphi }\cdot \sin \theta \cdot (715\cos ^{7}\theta -1001\cos ^{5}\theta +385\cos ^{3}\theta -35\cos \theta )\\Y_{8}^{0}(\theta ,\varphi )&={1 \over 256}{\sqrt {17 \over \pi }}\cdot (6435\cos ^{8}\theta -12012\cos ^{6}\theta +6930\cos ^{4}\theta -1260\cos ^{2}\theta +35)\\Y_{8}^{1}(\theta ,\varphi )&={-3 \over 64}{\sqrt {17 \over 2\pi }}\cdot \mathrm {e} ^{i\varphi }\cdot \sin \theta \cdot (715\cos ^{7}\theta -1001\cos ^{5}\theta +385\cos ^{3}\theta -35\cos \theta )\\Y_{8}^{2}(\theta ,\varphi )&={3 \over 128}{\sqrt {595 \over \pi }}\cdot \mathrm {e} ^{2i\varphi }\cdot \sin ^{2}\theta \cdot (143\cos ^{6}\theta -143\cos ^{4}\theta +33\cos ^{2}\theta -1)\\Y_{8}^{3}(\theta ,\varphi )&={-1 \over 64}{\sqrt {19635 \over 2\pi }}\cdot \mathrm {e} ^{3i\varphi }\cdot \sin ^{3}\theta \cdot (39\cos ^{5}\theta -26\cos ^{3}\theta +3\cos \theta )\\Y_{8}^{4}(\theta ,\varphi )&={3 \over 128}{\sqrt {1309 \over 2\pi }}\cdot \mathrm {e} ^{4i\varphi }\cdot \sin ^{4}\theta \cdot (65\cos ^{4}\theta -26\cos ^{2}\theta +1)\\Y_{8}^{5}(\theta ,\varphi )&={-3 \over 64}{\sqrt {17017 \over 2\pi }}\cdot \mathrm {e} ^{5i\varphi }\cdot \sin ^{5}\theta \cdot (5\cos ^{3}\theta -\cos \theta )\\Y_{8}^{6}(\theta ,\varphi )&={1 \over 128}{\sqrt {7293 \over \pi }}\cdot \mathrm {e} ^{6i\varphi }\cdot \sin ^{6}\theta \cdot (15\cos ^{2}\theta -1)\\Y_{8}^{7}(\theta ,\varphi )&={-3 \over 64}{\sqrt {12155 \over 2\pi }}\cdot \mathrm {e} ^{7i\varphi }\cdot \sin ^{7}\theta \cdot \cos \theta \\Y_{8}^{8}(\theta ,\varphi )&={3 \over 256}{\sqrt {12155 \over 2\pi }}\cdot \mathrm {e} ^{8i\varphi }\cdot \sin ^{8}\theta \end{aligned}}}

= 9

Y99(θ,φ)=1512230945πmi9iφpecado9θY98(θ,φ)=32562309452πmi8iφpecado8θporqueθY97(θ,φ)=351213585πmi7iφpecado7θ(17porque2θ1)Y96(θ,φ)=112840755πmi6iφpecado6θ(17porque3θ3porqueθ)Y95(θ,φ)=32562717πmi5iφpecado5θ(85porque4θ30porque2θ+1)Y94(θ,φ)=3128950952πmi4iφpecado4θ(17porque5θ10porque3θ+porqueθ)Y93(θ,φ)=125621945πmi3iφpecado3θ(221porque6θ195porque4θ+39porque2θ1)Y92(θ,φ)=31281045πmi2iφpecado2θ(221porque7θ273porque5θ+91porque3θ7porqueθ)Y91(θ,φ)=3256952πmiiφpecadoθ(2431porque8θ4004porque6θ+2002porque4θ308porque2θ+7)Y90(θ,φ)=125619π(12155porque9θ25740porque7θ+18018porque5θ4620porque3θ+315porqueθ)Y91(θ,φ)=3256952πmiiφpecadoθ(2431porque8θ4004porque6θ+2002porque4θ308porque2θ+7)Y92(θ,φ)=31281045πmi2iφpecado2θ(221porque7θ273porque5θ+91porque3θ7porqueθ)Y93(θ,φ)=125621945πmi3iφpecado3θ(221porque6θ195porque4θ+39porque2θ1)Y94(θ,φ)=3128950952πmi4iφpecado4θ(17porque5θ10porque3θ+porqueθ)Y95(θ,φ)=32562717πmi5iφpecado5θ(85porque4θ30porque2θ+1)Y96(θ,φ)=112840755πmi6iφpecado6θ(17porque3θ3porqueθ)Y97(θ,φ)=351213585πmi7iφpecado7θ(17porque2θ1)Y98(θ,φ)=32562309452πmi8iφpecado8θporqueθY99(θ,φ)=1512230945πmi9iφpecado9θ{\displaystyle {\begin{aligned}Y_{9}^{-9}(\theta ,\varphi )&={1 \over 512}{\sqrt {230945 \over \pi }}\cdot \mathrm {e} ^{-9i\varphi }\cdot \sin ^{9}\theta \\Y_{9}^{-8}(\theta ,\varphi )&={3 \over 256}{\sqrt {230945 \over 2\pi }}\cdot \mathrm {e} ^{-8i\varphi }\cdot \sin ^{8}\theta \cdot \cos \theta \\Y_{9}^{-7}(\theta ,\varphi )&={3 \over 512}{\sqrt {13585 \over \pi }}\cdot \mathrm {e} ^{-7i\varphi }\cdot \sin ^{7}\theta \cdot (17\cos ^{2}\theta -1)\\Y_{9}^{-6}(\theta ,\varphi )&={1 \over 128}{\sqrt {40755 \over \pi }}\cdot \mathrm {e} ^{-6i\varphi }\cdot \sin ^{6}\theta \cdot (17\cos ^{3}\theta -3\cos \theta )\\Y_{9}^{-5}(\theta ,\varphi )&={3 \over 256}{\sqrt {2717 \over \pi }}\cdot \mathrm {e} ^{-5i\varphi }\cdot \sin ^{5}\theta \cdot (85\cos ^{4}\theta -30\cos ^{2}\theta +1)\\Y_{9}^{-4}(\theta ,\varphi )&={3 \over 128}{\sqrt {95095 \over 2\pi }}\cdot e^{-4i\varphi }\cdot \sin ^{4}\theta \cdot (17\cos ^{5}\theta -10\cos ^{3}\theta +\cos \theta )\\Y_{9}^{-3}(\theta ,\varphi )&={1 \over 256}{\sqrt {21945 \over \pi }}\cdot \mathrm {e} ^{-3i\varphi }\cdot \sin ^{3}\theta \cdot (221\cos ^{6}\theta -195\cos ^{4}\theta +39\cos ^{2}\theta -1)\\Y_{9}^{-2}(\theta ,\varphi )&={3 \over 128}{\sqrt {1045 \over \pi }}\cdot \mathrm {e} ^{-2i\varphi }\cdot \sin ^{2}\theta \cdot (221\cos ^{7}\theta -273\cos ^{5}\theta +91\cos ^{3}\theta -7\cos \theta )\\Y_{9}^{-1}(\theta ,\varphi )&={3 \over 256}{\sqrt {95 \over 2\pi }}\cdot \mathrm {e} ^{-i\varphi }\cdot \sin \theta \cdot (2431\cos ^{8}\theta -4004\cos ^{6}\theta +2002\cos ^{4}\theta -308\cos ^{2}\theta +7)\\Y_{9}^{0}(\theta ,\varphi )&={1 \over 256}{\sqrt {19 \over \pi }}\cdot (12155\cos ^{9}\theta -25740\cos ^{7}\theta +18018\cos ^{5}\theta -4620\cos ^{3}\theta +315\cos \theta )\\Y_{9}^{1}(\theta ,\varphi )&={-3 \over 256}{\sqrt {95 \over 2\pi }}\cdot \mathrm {e} ^{i\varphi }\cdot \sin \theta \cdot (2431\cos ^{8}\theta -4004\cos ^{6}\theta +2002\cos ^{4}\theta -308\cos ^{2}\theta +7)\\Y_{9}^{2}(\theta ,\varphi )&={3 \over 128}{\sqrt {1045 \over \pi }}\cdot \mathrm {e} ^{2i\varphi }\cdot \sin ^{2}\theta \cdot (221\cos ^{7}\theta -273\cos ^{5}\theta +91\cos ^{3}\theta -7\cos \theta )\\Y_{9}^{3}(\theta ,\varphi )&={-1 \over 256}{\sqrt {21945 \over \pi }}\cdot \mathrm {e} ^{3i\varphi }\cdot \sin ^{3}\theta \cdot (221\cos ^{6}\theta -195\cos ^{4}\theta +39\cos ^{2}\theta -1)\\Y_{9}^{4}(\theta ,\varphi )&={3 \over 128}{\sqrt {95095 \over 2\pi }}\cdot \mathrm {e} ^{4i\varphi }\cdot \sin ^{4}\theta \cdot (17\cos ^{5}\theta -10\cos ^{3}\theta +\cos \theta )\\Y_{9}^{5}(\theta ,\varphi )&={-3 \over 256}{\sqrt {2717 \over \pi }}\cdot \mathrm {e} ^{5i\varphi }\cdot \sin ^{5}\theta \cdot (85\cos ^{4}\theta -30\cos ^{2}\theta +1)\\Y_{9}^{6}(\theta ,\varphi )&={1 \over 128}{\sqrt {40755 \over \pi }}\cdot \mathrm {e} ^{6i\varphi }\cdot \sin ^{6}\theta \cdot (17\cos ^{3}\theta -3\cos \theta )\\Y_{9}^{7}(\theta ,\varphi )&={-3 \over 512}{\sqrt {13585 \over \pi }}\cdot \mathrm {e} ^{7i\varphi }\cdot \sin ^{7}\theta \cdot (17\cos ^{2}\theta -1)\\Y_{9}^{8}(\theta ,\varphi )&={3 \over 256}{\sqrt {230945 \over 2\pi }}\cdot \mathrm {e} ^{8i\varphi }\cdot \sin ^{8}\theta \cdot \cos \theta \\Y_{9}^{9}(\theta ,\varphi )&={-1 \over 512}{\sqrt {230945 \over \pi }}\cdot \mathrm {e} ^{9i\varphi }\cdot \sin ^{9}\theta \end{aligned}}}

= 10

Y1010(θ,φ)=11024969969πmi10iφpecado10θY109(θ,φ)=15124849845πmi9iφpecado9θporqueθY108(θ,φ)=15122552552πmi8iφpecado8θ(19porque2θ1)Y107(θ,φ)=351285085πmi7iφpecado7θ(19porque3θ3porqueθ)Y106(θ,φ)=310245005πmi6iφpecado6θ(323porque4θ102porque2θ+3)Y105(θ,φ)=32561001πmi5iφpecado5θ(323porque5θ170porque3θ+15porqueθ)Y104(θ,φ)=325650052πmi4iφpecado4θ(323porque6θ255porque4θ+45porque2θ1)Y103(θ,φ)=32565005πmi3iφpecado3θ(323porque7θ357porque5θ+105porque3θ7porqueθ)Y102(θ,φ)=35123852πmi2iφpecado2θ(4199porque8θ6188porque6θ+2730porque4θ364porque2θ+7)Y101(θ,φ)=125611552πmiiφpecadoθ(4199porque9θ7956porque7θ+4914porque5θ1092porque3θ+63porqueθ)Y100(θ,φ)=151221π(46189porque10θ109395porque8θ+90090porque6θ30030porque4θ+3465porque2θ63)Y101(θ,φ)=125611552πmiiφpecadoθ(4199porque9θ7956porque7θ+4914porque5θ1092porque3θ+63porqueθ)Y102(θ,φ)=35123852πmi2iφpecado2θ(4199porque8θ6188porque6θ+2730porque4θ364porque2θ+7)Y103(θ,φ)=32565005πmi3iφpecado3θ(323porque7θ357porque5θ+105porque3θ7porqueθ)Y104(θ,φ)=325650052πmi4iφpecado4θ(323porque6θ255porque4θ+45porque2θ1)Y105(θ,φ)=32561001πmi5iφpecado5θ(323porque5θ170porque3θ+15porqueθ)Y106(θ,φ)=310245005πmi6iφpecado6θ(323porque4θ102porque2θ+3)Y107(θ,φ)=351285085πmi7iφpecado7θ(19porque3θ3porqueθ)Y108(θ,φ)=15122552552πmi8iφpecado8θ(19porque2θ1)Y109(θ,φ)=15124849845πmi9iφpecado9θporqueθY1010(θ,φ)=11024969969πmi10iφpecado10θ{\displaystyle {\begin{aligned}Y_{10}^{-10}(\theta ,\varphi )&={1 \over 1024}{\sqrt {969969 \over \pi }}\cdot \mathrm {e} ^{-10i\varphi }\cdot \sin ^{10}\theta \\Y_{10}^{-9}(\theta ,\varphi )&={1 \over 512}{\sqrt {4849845 \over \pi }}\cdot \mathrm {e} ^{-9i\varphi }\cdot \sin ^{9}\theta \cdot \cos \theta \\Y_{10}^{-8}(\theta ,\varphi )&={1 \over 512}{\sqrt {255255 \over 2\pi }}\cdot \mathrm {e} ^{-8i\varphi }\cdot \sin ^{8}\theta \cdot (19\cos ^{2}\theta -1)\\Y_{10}^{-7}(\theta ,\varphi )&={3 \over 512}{\sqrt {85085 \over \pi }}\cdot \mathrm {e} ^{-7i\varphi }\cdot \sin ^{7}\theta \cdot (19\cos ^{3}\theta -3\cos \theta )\\Y_{10}^{-6}(\theta ,\varphi )&={3 \over 1024}{\sqrt {5005 \over \pi }}\cdot \mathrm {e} ^{-6i\varphi }\cdot \sin ^{6}\theta \cdot (323\cos ^{4}\theta -102\cos ^{2}\theta +3)\\Y_{10}^{-5}(\theta ,\varphi )&={3 \over 256}{\sqrt {1001 \over \pi }}\cdot \mathrm {e} ^{-5i\varphi }\cdot \sin ^{5}\theta \cdot (323\cos ^{5}\theta -170\cos ^{3}\theta +15\cos \theta )\\Y_{10}^{-4}(\theta ,\varphi )&={3 \over 256}{\sqrt {5005 \over 2\pi }}\cdot \mathrm {e} ^{-4i\varphi }\cdot \sin ^{4}\theta \cdot (323\cos ^{6}\theta -255\cos ^{4}\theta +45\cos ^{2}\theta -1)\\Y_{10}^{-3}(\theta ,\varphi )&={3 \over 256}{\sqrt {5005 \over \pi }}\cdot \mathrm {e} ^{-3i\varphi }\cdot \sin ^{3}\theta \cdot (323\cos ^{7}\theta -357\cos ^{5}\theta +105\cos ^{3}\theta -7\cos \theta )\\Y_{10}^{-2}(\theta ,\varphi )&={3 \over 512}{\sqrt {385 \over 2\pi }}\cdot \mathrm {e} ^{-2i\varphi }\cdot \sin ^{2}\theta \cdot (4199\cos ^{8}\theta -6188\cos ^{6}\theta +2730\cos ^{4}\theta -364\cos ^{2}\theta +7)\\Y_{10}^{-1}(\theta ,\varphi )&={1 \over 256}{\sqrt {1155 \over 2\pi }}\cdot \mathrm {e} ^{-i\varphi }\cdot \sin \theta \cdot (4199\cos ^{9}\theta -7956\cos ^{7}\theta +4914\cos ^{5}\theta -1092\cos ^{3}\theta +63\cos \theta )\\Y_{10}^{0}(\theta ,\varphi )&={1 \over 512}{\sqrt {21 \over \pi }}\cdot (46189\cos ^{10}\theta -109395\cos ^{8}\theta +90090\cos ^{6}\theta -30030\cos ^{4}\theta +3465\cos ^{2}\theta -63)\\Y_{10}^{1}(\theta ,\varphi )&={-1 \over 256}{\sqrt {1155 \over 2\pi }}\cdot \mathrm {e} ^{i\varphi }\cdot \sin \theta \cdot (4199\cos ^{9}\theta -7956\cos ^{7}\theta +4914\cos ^{5}\theta -1092\cos ^{3}\theta +63\cos \theta )\\Y_{10}^{2}(\theta ,\varphi )&={3 \over 512}{\sqrt {385 \over 2\pi }}\cdot \mathrm {e} ^{2i\varphi }\cdot \sin ^{2}\theta \cdot (4199\cos ^{8}\theta -6188\cos ^{6}\theta +2730\cos ^{4}\theta -364\cos ^{2}\theta +7)\\Y_{10}^{3}(\theta ,\varphi )&={-3 \over 256}{\sqrt {5005 \over \pi }}\cdot \mathrm {e} ^{3i\varphi }\cdot \sin ^{3}\theta \cdot (323\cos ^{7}\theta -357\cos ^{5}\theta +105\cos ^{3}\theta -7\cos \theta )\\Y_{10}^{4}(\theta ,\varphi )&={3 \over 256}{\sqrt {5005 \over 2\pi }}\cdot \mathrm {e} ^{4i\varphi }\cdot \sin ^{4}\theta \cdot (323\cos ^{6}\theta -255\cos ^{4}\theta +45\cos ^{2}\theta -1)\\Y_{10}^{5}(\theta ,\varphi )&={-3 \over 256}{\sqrt {1001 \over \pi }}\cdot \mathrm {e} ^{5i\varphi }\cdot \sin ^{5}\theta \cdot (323\cos ^{5}\theta -170\cos ^{3}\theta +15\cos \theta )\\Y_{10}^{6}(\theta ,\varphi )&={3 \over 1024}{\sqrt {5005 \over \pi }}\cdot \mathrm {e} ^{6i\varphi }\cdot \sin ^{6}\theta \cdot (323\cos ^{4}\theta -102\cos ^{2}\theta +3)\\Y_{10}^{7}(\theta ,\varphi )&={-3 \over 512}{\sqrt {85085 \over \pi }}\cdot \mathrm {e} ^{7i\varphi }\cdot \sin ^{7}\theta \cdot (19\cos ^{3}\theta -3\cos \theta )\\Y_{10}^{8}(\theta ,\varphi )&={1 \over 512}{\sqrt {255255 \over 2\pi }}\cdot \mathrm {e} ^{8i\varphi }\cdot \sin ^{8}\theta \cdot (19\cos ^{2}\theta -1)\\Y_{10}^{9}(\theta ,\varphi )&={-1 \over 512}{\sqrt {4849845 \over \pi }}\cdot \mathrm {e} ^{9i\varphi }\cdot \sin ^{9}\theta \cdot \cos \theta \\Y_{10}^{10}(\theta ,\varphi )&={1 \over 1024}{\sqrt {969969 \over \pi }}\cdot \mathrm {e} ^{10i\varphi }\cdot \sin ^{10}\theta \end{aligned}}}

Visualización de armónicos esféricos complejos

Mapas de ángulo polar/azimutal en 2D

A continuación se representan los armónicos esféricos complejos en gráficos 2D con el ángulo azimutal,ϕ{\displaystyle \phi }, en el eje horizontal y el ángulo polar,θ{\displaystyle \theta }, en el eje vertical. La saturación del color en cualquier punto representa la magnitud del armónico esférico y el tono representa la fase.

Las líneas nodales de latitud se visualizan como líneas blancas horizontales. Las líneas nodales de longitud se visualizan como líneas blancas verticales.

Representación visual de armónicos esféricos complejos como mapas theta/phi bidimensionales.

Diagramas polares

A continuación se representan los armónicos esféricos complejos en diagramas polares. La magnitud del armónico esférico en ángulos polares y azimutales específicos se representa mediante la saturación del color en ese punto, y la fase se representa mediante el tono en ese punto.

Representación visual de armónicos esféricos complejos mediante un diagrama polar.

Gráficos polares con magnitud como radio

A continuación se representan los armónicos esféricos complejos en diagramas polares. La magnitud del armónico esférico en ángulos polares y azimutales específicos se representa mediante el radio del diagrama en ese punto, y la fase se representa mediante el tono en ese punto.

Representación visual de armónicos esféricos complejos mediante un gráfico polar con magnitud mapeada al radio.

Armónicos esféricos reales

Para cada armónico esférico real, también se informa el símbolo del orbital atómico correspondiente ( s , p , d , f ). [ 2 ] [ 3 ]

Para = 0, …, 3, véase. [ 4 ] [ 5 ]

= 0

Y0,0=s=Y00=121π{\displaystyle Y_{0,0}=s=Y_{0}^{0}={\frac {1}{2}}{\sqrt {\frac {1}{\pi }}}}

= 1

Y1,1=pagy=i12(Y11+Y11)=34πyr=34πpecado(θ)pecado(φ)Y1,0=pagz=Y10=34πzr=34πporque(θ)Y1,1=pagincógnita=12(Y11Y11)=34πincógnitar=34πpecado(θ)porque(φ){\displaystyle {\begin{aligned}Y_{1,-1}&=p_{y}=i{\sqrt {\frac {1}{2}}}\left(Y_{1}^{-1}+Y_{1}^{1}\right)={\sqrt {\frac {3}{4\pi }}}\cdot {\frac {y}{r}}={\sqrt {\frac {3}{4\pi }}}\sin(\theta )\sin(\varphi )\\Y_{1,0}&=p_{z}=Y_{1}^{0}={\sqrt {\frac {3}{4\pi }}}\cdot {\frac {z}{r}}={\sqrt {\frac {3}{4\pi }}}\cos(\theta )\\Y_{1,1}&=p_{x}={\sqrt {\frac {1}{2}}}\left(Y_{1}^{-1}-Y_{1}^{1}\right)={\sqrt {\frac {3}{4\pi }}}\cdot {\frac {x}{r}}={\sqrt {\frac {3}{4\pi }}}\sin(\theta )\cos(\varphi )\end{aligned}}}

= 2

Y2,2=dincógnitay=i12(Y22Y22)=1215πincógnitayr2=1415πpecado2(θ)pecado(2φ)Y2,1=dyz=i12(Y21+Y21)=1215πyzr2=1415πpecado(2θ)pecado(φ)Y2,0=dz2=Y20=145π3z2r2r2=145π(3porque2(θ)1)Y2,1=dincógnitaz=12(Y21Y21)=1215πincógnitazr2=1415πpecado(2θ)porque(φ)Y2,2=dincógnita2y2=12(Y22+Y22)=1415πincógnita2y2r2=1415πpecado2(θ)porque(2φ){\displaystyle {\begin{aligned}Y_{2,-2}&=d_{xy}=i{\sqrt {\frac {1}{2}}}\left(Y_{2}^{-2}-Y_{2}^{2}\right)={\frac {1}{2}}{\sqrt {\frac {15}{\pi }}}\cdot {\frac {xy}{r^{2}}}={\frac {1}{4}}{\sqrt {\frac {15}{\pi }}}\sin ^{2}(\theta )\sin(2\varphi )\\Y_{2,-1}&=d_{yz}=i{\sqrt {\frac {1}{2}}}\left(Y_{2}^{-1}+Y_{2}^{1}\right)={\frac {1}{2}}{\sqrt {\frac {15}{\pi }}}\cdot {\frac {y\cdot z}{r^{2}}}={\frac {1}{4}}{\sqrt {\frac {15}{\pi }}}\sin(2\theta )\sin(\varphi )\\Y_{2,0}&=d_{z^{2}}=Y_{2}^{0}={\frac {1}{4}}{\sqrt {\frac {5}{\pi }}}\cdot {\frac {3z^{2}-r^{2}}{r^{2}}}={\frac {1}{4}}{\sqrt {\frac {5}{\pi }}}(3\cos ^{2}(\theta )-1)\\Y_{2,1}&=d_{xz}={\sqrt {\frac {1}{2}}}\left(Y_{2}^{-1}-Y_{2}^{1}\right)={\frac {1}{2}}{\sqrt {\frac {15}{\pi }}}\cdot {\frac {x\cdot z}{r^{2}}}={\frac {1}{4}}{\sqrt {\frac {15}{\pi }}}\sin(2\theta )\cos(\varphi )\\Y_{2,2}&=d_{x^{2}-y^{2}}={\sqrt {\frac {1}{2}}}\left(Y_{2}^{-2}+Y_{2}^{2}\right)={\frac {1}{4}}{\sqrt {\frac {15}{\pi }}}\cdot {\frac {x^{2}-y^{2}}{r^{2}}}={\frac {1}{4}}{\sqrt {\frac {15}{\pi }}}\sin ^{2}(\theta )\cos(2\varphi )\end{aligned}}}

= 3

Y3,3=Fy(3incógnita2y2)=i12(Y33+Y33)=14352πy(3incógnita2y2)r3Y3,2=Fincógnitayz=i12(Y32Y32)=12105πincógnitayzr3Y3,1=Fyz2=i12(Y31+Y31)=14212πy(5z2r2)r3Y3,0=Fz3=Y30=147π5z33zr2r3Y3,1=Fincógnitaz2=12(Y31Y31)=14212πincógnita(5z2r2)r3Y3,2=Fz(incógnita2y2)=12(Y32+Y32)=14105π(incógnita2y2)zr3Y3,3=Fincógnita(incógnita23y2)=12(Y33Y33)=14352πincógnita(incógnita23y2)r3{\displaystyle {\begin{aligned}Y_{3,-3}&=f_{y(3x^{2}-y^{2})}=i{\sqrt {\frac {1}{2}}}\left(Y_{3}^{-3}+Y_{3}^{3}\right)={\frac {1}{4}}{\sqrt {\frac {35}{2\pi }}}\cdot {\frac {y\left(3x^{2}-y^{2}\right)}{r^{3}}}\\Y_{3,-2}&=f_{xyz}=i{\sqrt {\frac {1}{2}}}\left(Y_{3}^{-2}-Y_{3}^{2}\right)={\frac {1}{2}}{\sqrt {\frac {105}{\pi }}}\cdot {\frac {xy\cdot z}{r^{3}}}\\Y_{3,-1}&=f_{yz^{2}}=i{\sqrt {\frac {1}{2}}}\left(Y_{3}^{-1}+Y_{3}^{1}\right)={\frac {1}{4}}{\sqrt {\frac {21}{2\pi }}}\cdot {\frac {y\cdot (5z^{2}-r^{2})}{r^{3}}}\\Y_{3,0}&=f_{z^{3}}=Y_{3}^{0}={\frac {1}{4}}{\sqrt {\frac {7}{\pi }}}\cdot {\frac {5z^{3}-3zr^{2}}{r^{3}}}\\Y_{3,1}&=f_{xz^{2}}={\sqrt {\frac {1}{2}}}\left(Y_{3}^{-1}-Y_{3}^{1}\right)={\frac {1}{4}}{\sqrt {\frac {21}{2\pi }}}\cdot {\frac {x\cdot (5z^{2}-r^{2})}{r^{3}}}\\Y_{3,2}&=f_{z(x^{2}-y^{2})}={\sqrt {\frac {1}{2}}}\left(Y_{3}^{-2}+Y_{3}^{2}\right)={\frac {1}{4}}{\sqrt {\frac {105}{\pi }}}\cdot {\frac {\left(x^{2}-y^{2}\right)\cdot z}{r^{3}}}\\Y_{3,3}&=f_{x(x^{2}-3y^{2})}={\sqrt {\frac {1}{2}}}\left(Y_{3}^{-3}-Y_{3}^{3}\right)={\frac {1}{4}}{\sqrt {\frac {35}{2\pi }}}\cdot {\frac {x\left(x^{2}-3y^{2}\right)}{r^{3}}}\end{aligned}}}

= 4

Y4,4=i12(Y44Y44)=3435πincógnitay(incógnita2y2)r4Y4,3=i12(Y43+Y43)=34352πy(3incógnita2y2)zr4Y4,2=i12(Y42Y42)=345πincógnitay(7z2r2)r4Y4,1=i12(Y41+Y41)=3452πy(7z33zr2)r4Y4,0=Y40=3161π35z430z2r2+3r4r4Y4,1=12(Y41Y41)=3452πincógnita(7z33zr2)r4Y4,2=12(Y42+Y42)=385π(incógnita2y2)(7z2r2)r4Y4,3=12(Y43Y43)=34352πincógnita(incógnita23y2)zr4Y4,4=12(Y44+Y44)=31635πincógnita2(incógnita23y2)y2(3incógnita2y2)r4{\displaystyle {\begin{aligned}Y_{4,-4}&=i{\sqrt {\frac {1}{2}}}\left(Y_{4}^{-4}-Y_{4}^{4}\right)={\frac {3}{4}}{\sqrt {\frac {35}{\pi }}}\cdot {\frac {xy\left(x^{2}-y^{2}\right)}{r^{4}}}\\Y_{4,-3}&=i{\sqrt {\frac {1}{2}}}\left(Y_{4}^{-3}+Y_{4}^{3}\right)={\frac {3}{4}}{\sqrt {\frac {35}{2\pi }}}\cdot {\frac {y(3x^{2}-y^{2})\cdot z}{r^{4}}}\\Y_{4,-2}&=i{\sqrt {\frac {1}{2}}}\left(Y_{4}^{-2}-Y_{4}^{2}\right)={\frac {3}{4}}{\sqrt {\frac {5}{\pi }}}\cdot {\frac {xy\cdot (7z^{2}-r^{2})}{r^{4}}}\\Y_{4,-1}&=i{\sqrt {\frac {1}{2}}}\left(Y_{4}^{-1}+Y_{4}^{1}\right)={\frac {3}{4}}{\sqrt {\frac {5}{2\pi }}}\cdot {\frac {y\cdot (7z^{3}-3zr^{2})}{r^{4}}}\\Y_{4,0}&=Y_{4}^{0}={\frac {3}{16}}{\sqrt {\frac {1}{\pi }}}\cdot {\frac {35z^{4}-30z^{2}r^{2}+3r^{4}}{r^{4}}}\\Y_{4,1}&={\sqrt {\frac {1}{2}}}\left(Y_{4}^{-1}-Y_{4}^{1}\right)={\frac {3}{4}}{\sqrt {\frac {5}{2\pi }}}\cdot {\frac {x\cdot (7z^{3}-3zr^{2})}{r^{4}}}\\Y_{4,2}&={\sqrt {\frac {1}{2}}}\left(Y_{4}^{-2}+Y_{4}^{2}\right)={\frac {3}{8}}{\sqrt {\frac {5}{\pi }}}\cdot {\frac {(x^{2}-y^{2})\cdot (7z^{2}-r^{2})}{r^{4}}}\\Y_{4,3}&={\sqrt {\frac {1}{2}}}\left(Y_{4}^{-3}-Y_{4}^{3}\right)={\frac {3}{4}}{\sqrt {\frac {35}{2\pi }}}\cdot {\frac {x(x^{2}-3y^{2})\cdot z}{r^{4}}}\\Y_{4,4}&={\sqrt {\frac {1}{2}}}\left(Y_{4}^{-4}+Y_{4}^{4}\right)={\frac {3}{16}}{\sqrt {\frac {35}{\pi }}}\cdot {\frac {x^{2}\left(x^{2}-3y^{2}\right)-y^{2}\left(3x^{2}-y^{2}\right)}{r^{4}}}\end{aligned}}}

Visualización de armónicos esféricos reales

Mapas de ángulo polar/azimutal en 2D

A continuación se representan los armónicos esféricos reales en gráficos 2D con el ángulo azimutal,ϕ{\displaystyle \phi }, en el eje horizontal y el ángulo polar,θ{\displaystyle \theta }, en el eje vertical. La saturación del color en cualquier punto representa la magnitud del armónico esférico. Los valores positivos son rojos y los negativos son verde azulado.

Las líneas nodales de latitud se visualizan como líneas blancas horizontales. Las líneas nodales de longitud se visualizan como líneas blancas verticales.

Representación visual de armónicos esféricos reales como mapas theta/phi bidimensionales.

Diagramas polares

A continuación se representan los armónicos esféricos reales en diagramas polares. La magnitud del armónico esférico en ángulos polares y azimutales específicos se representa mediante la saturación del color en ese punto, y la fase se representa mediante el tono en ese punto.

Representación visual de armónicos esféricos reales mediante un diagrama polar.

Gráficos polares con magnitud como radio

A continuación se representan los armónicos esféricos reales en diagramas polares. La magnitud del armónico esférico en ángulos polares y azimutales específicos se representa mediante el radio del diagrama en ese punto, y la fase se representa mediante el tono en ese punto.

Representación visual de armónicos esféricos reales mediante un diagrama polar con la magnitud mapeada al radio.

Gráficos polares con amplitud como elevación

A continuación se muestran los armónicos esféricos reales representados en diagramas polares. La amplitud del armónico esférico (magnitud y signo) en un ángulo polar y azimutal determinado se representa mediante la elevación del diagrama en ese punto, por encima o por debajo de la superficie de una esfera uniforme. La magnitud también se representa mediante la saturación del color en un punto dado. La fase se representa mediante el tono en un punto dado.

Representación visual de armónicos esféricos reales mediante un diagrama polar con amplitud mapeada a elevación y saturación.

Véase también

  • Armónicos esféricos en MathWorld
  • Representación 3D de armónicos esféricos

Referencias

Referencias citadas

  1. DA Varshalovich; AN Moskalev; VK Khersonskii (1988). Teoría cuántica del momento angular  : tensores irreducibles, armónicos esféricos, coeficientes de acoplamiento vectorial, símbolos 3nj (1.ª ed. reimpr  .). Singapur: World Scientific Pub. pp. 155–156 . ISBN  9971-50-107-4.
  2. Petrucci (2016). Química general : principios y aplicaciones modernas . Prentice Hall. ISBN  0133897311.
  3. Friedman (1964). "Las formas de los orbitales f". J. Chem. Educ . 41 (7): 354.
  4. CDH Chisholm (1976). Técnicas de teoría de grupos en química cuántica . Nueva York: Academic Press. ISBN 0-12-172950-8.
  5. Blanco, Miguel A.; Flórez, M.; Bermejo, M. (1 de diciembre de 1997). "Evaluación de las matrices de rotación en la base de armónicos esféricos reales". Journal of Molecular Structure: THEOCHEM . 419 ( 1–3 ): 19–27 . doi : 10.1016/S0166-1280(97)00185-1 .

Referencias generales

  • Véase la sección 3 en Mathar, RJ (2009). "Base de Zernike para transformaciones cartesianas". Revista Astronómica Serbia . 179 (179): 107– 120. arXiv : 0809.2368 . Bibcode : 2009SerAJ.179..107M . doi : 10.2298/SAJ0979107M .(véase la sección 3.3)
  • Para armónicos esféricos complejos, consulte también SphericalHarmonicY[l,m,theta,phi ] en Wolfram Alpha , especialmente para valores específicos de l y m.