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1-Hexadecene

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1-Hexadecene, also known as 1-cetene, is a long-chain hydrocarbon and an alkene with the molecular formula CH2=CH(CH2)13CH3. It is one of many isomers of hexadecene. Classified as an alpha-olefin, 1-hexadecene is a colorless liquid.[3][4][5]

Uses

1-Hexadecene is used as a surfactant in lubricating fluid, a drilling fluid in the boring and drilling industry, and in paper sizing.[2] It is used to functionalize hydrogen-terminated silicon surfaces by hydrosilation.[6]

However, the high reactivity of 1-hexadecene means that exposure to air could cause oxidation of its surface layer, forming unwanted impurities. It is stored with the use of tank blanketing, and handled in a dry, inert atmosphere.[4]

References

  1. 12"1-Hexadecene for synthesis. CAS 629-73-2, chemical formula CH3(CH2)13CH=CH2". merckmillipore.com. Retrieved 2021-02-14.
  2. 123"AlphaPlus 1-Hexadecene Safety Data Sheet"(PDF). Archived from the original(PDF) on 2019-09-24.
  3. ↑Griesbaum, Karl; Behr, Arno; Biedenkapp, Dieter; Voges, Heinz-Werner; Garbe, Dorothea; Paetz, Christian; Collin, Gerd; Mayer, Dieter; Höke, Hartmut (2000). "Hydrocarbons". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a13_227. ISBN 3527306730.
  4. 12"1-Hexacedene (Alpha Olefin C16)". Archived from the original on 2017-08-25. Retrieved 2017-07-07.
  5. ↑"1-HEXADECENE (ALPHA-OLEFIN C16)". chemicalland21.com. Retrieved 2021-02-14.
  6. ↑Sieval, A. B.; Demirel, A. L.; Nissink, J. W. M.; Linford, M. R.; Van Der Maas, J. H.; De Jeu, W. H.; Zuilhof, H.; Sudhölter, E. J. R. (1998). "Highly Stable Si−C Linked Functionalized Monolayers on the Silicon (100) Surface". Langmuir. 14 (7): 1759–1768. doi:10.1021/la971139z.